Exfoliated graphite preparation based on an eco-friendly mechanochemical route

Abstract

In the present study, we proposed an eco-friendly method to produce exfoliated graphite based on a dry mechanochemical process. This route represents an alternative that avoids the use and disposal problems related to highly corrosive and dangerous reagents use, manipulation and elimination. As non-toxic alternative exfoliation route, an equimolar mixture of graphite flakes and calcium carbonate was milled and leached with an aqueous solution of acetic acid (vinegar). There was a notable reduction of the graphite particle size with a significantly increased level of exfoliation, which dramatically improved the surface area of the prepared samples from 4 to 363 m2 g-1. After 16 h of processing, milled particles reached a thickness reduction of up to 5 nm and micrometric widths.The overall yield of processed graphite is around 92% based on the raw graphite. The evident benefits of the obtained exfoliated graphites in the adsorption of methylene blue (a common pollutant of textile wastewater) are presented. Exfoliated graphite represents a valid alternative as adsorption agent for dye removal reaching efficiencies above 95% after 30 min of testing with an aqueous solution of methylene blue. Contrary, the untreated graphite sample showed a null adsorption activity.