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dc.contributor.author | Zhang, Xuan | |
dc.contributor.author | Xie, Haomiao | |
dc.contributor.author | BALLESTEROS RIVAS, MARIA FERNANDA | |
dc.contributor.author | Wang, Zhao-xi | |
dc.contributor.author | Dunbar, Kim Renee | |
dc.creator | Zhang, Xuan;#0000-0001-5684-3064 | |
dc.creator | Xie, Haomiao;#0000-0001-7688-6571 | |
dc.creator | BALLESTEROS RIVAS, MARIA FERNANDA; 177336 | |
dc.creator | Wang, Zhao-xi;#0000-0003-4644-7935 | |
dc.creator | Dunbar, Kim Renee;#0000-0001-7170-3908 | |
dc.date.accessioned | 2018-02-16T20:12:22Z | |
dc.date.available | 2018-02-16T20:12:22Z | |
dc.date.issued | 2015-08-13 | |
dc.identifier.issn | 2050-7526 | |
dc.identifier.uri | http://hdl.handle.net/20.500.11799/68647 | |
dc.description.abstract | The incorporation of TCNQ˙− (7,7,8,8-tetracyanoquinodimethane) radicals as counterions for the spin-crossover material [Co(pyterpy)2](TCNQ)2·solvent (pyterpy = 4′-(4′′′-pyridyl)-2,2′:6′,2′′-terpyridine) leads to structural distortions of the [Co(pyterpy)2]2+ spin-crossover cation as compared to [Co(pyterpy)2](PF6)2. Variable temperature structural and magnetic studies indicate that the supramolecular π-stacking interactions between the terminal pyridyl groups and TCNQ radicals play a crucial role in the spin-crossover properties. | es |
dc.language.iso | eng | es |
dc.publisher | royal chemical society | es |
dc.relation.ispartofseries | 3, 9292-9298; | |
dc.rights | openAccess | es |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0 | |
dc.subject | supramoleculares | es |
dc.subject | grupos piridilo terminales | es |
dc.subject | distorsiones estructurales | es |
dc.subject | spin-crossover | es |
dc.subject.classification | BIOLOGÍA Y QUÍMICA | |
dc.title | Structural distortions of the spin-crossover material [Co(pyterpy)2](TCNQ)2 mediated by supramolecular interactions. | es |
dc.type | Artículo | es |
dc.provenance | Científica | es |
dc.road | Dorada | es |
dc.ambito | Nacional | es |
dc.audience | students | es |
dc.audience | researchers | es |
dc.type.conacyt | article | |
dc.identificator | 2 |