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| dc.contributor.author | woods, Toby James
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| dc.contributor.author | Ballesteros-Rivas, Maria fernanda
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| dc.contributor.author | Ostrovsky, S M.
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| dc.contributor.author | Palii, A. V.
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| dc.contributor.author | Reu, O. S
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| dc.contributor.author | Klokishner, s. I
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| dc.contributor.author | Dunbar, Kim Renee
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| dc.date.accessioned | 2018-02-16T20:50:02Z | |
| dc.date.available | 2018-02-16T20:50:02Z | |
| dc.date.issued | 2015-06-12 | |
| dc.identifier.issn | 1521-3765 | |
| dc.identifier.uri | http://hdl.handle.net/20.500.11799/68665 | |
| dc.description | artículo científico | es |
| dc.description.abstract | The ligand-centered radical complex [(CoTPMA)2-μ-bmtz.−](O3SCF3)3⋅CH3CN (bmtz=3,6-bis(2′-pyrimidyl)-1,2,4,5-tetrazine, TPMA=tris-(2-pyridylmethyl)amine) has been synthesized from the neutral bmtz precursor. Single-crystal X-ray diffraction studies have confirmed the presence of the ligand-centered radical. The CoII complex exhibits slow paramagnetic relaxation in an applied DC field with a barrier to spin reversal of 39 K. This behavior is a result of strong antiferromagnetic metal–radical coupling combined with positive axial and strong rhombic anisotropic contributions from the CoII ions. | es |
| dc.description.sponsorship | National Science Foundation Ciencia y Tecnolog a del Distrito Federal (ICyTDF) STCU | es |
| dc.language.iso | eng | es |
| dc.publisher | Wiley VCH | es |
| dc.relation.ispartofseries | 21, 10302-10305; | |
| dc.rights | embargoedAccess | es |
| dc.rights | No aplica | es |
| dc.rights | embargoedAccess | es |
| dc.rights | No aplica | es |
| dc.title | Strong Direct Magnetic Coupling in a Dinuclear CoII Tetrazine Radical Single-Molecule Magnet. | es |
| dc.type | Artículo | es |
| dc.provenance | Científica | es |
| dc.road | Dorada | es |
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